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• W2016757141 abstract "In order to obtain optically active fluorinated propargyl alcohols, a lipase-catalyzed kinetic resolution has been carried out. The effect of lipase types, organic solvents, reaction temperature, and acyl donors was examined in the lipase-catalyzed transesterification of 1,1,1-trifluoro-4-phenyl-3-butyn-2-ol. Various enantiomerically pure fluorinated propargyl alcohols have been successfully prepared in good enantiomeric excess (>84%) by Novozym 435-catalyzed transesterification with vinyl butanoate at 60 °C in n-hexane. In some cases, the enantiomeric purities were excellent (>99% ee)." @default.
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• W2016757141 date "2009-06-01" @default.
• W2016757141 modified "2023-09-30" @default.
• W2016757141 title "Kinetic resolution of fluorinated propargyl alcohols by lipase-catalyzed enantioselective transesterification" @default.
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• W2016757141 doi "https://doi.org/10.1016/j.tetasy.2009.03.041" @default.
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