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- W2016761798 abstract "5,5'-Dinitro-3-diethylaminomethyl-2,2'-biphenol (1) and 5,5'-dinitro-3,3' bis(diethylaminomethyl)-2,2'-biphenol (2) as well as 5,5'-dinitro-2,2'-biphenol (3) were synthesized and studied by FT-IR and 1H NMR spectroscopy in acetonitrile or acetonitrile-d3 solutions, respectively. With compound 1 a hydrogen-bonded system with large proton polarizability is found. In the hydrogen bonds in compound 2 the protons are localized at the N atoms. These hydrogen bonds show no proton polarizability. In the protonated compound 2 a very strong homoconjugated −O⋯H+⋯O− hydrogen bond with large proton polarizability is found, whereas two other protons are localized at the N atoms. The deviation of the results obtained with other derivatives of 2,2'-biphenols are caused by the larger acidity of the nitro groups." @default.
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- W2016761798 date "1997-11-01" @default.
- W2016761798 modified "2023-10-18" @default.
- W2016761798 title "Hydrogen bonds and a hydrogen-bonded chain in mannich bases of 5,5'-dinitro-2,2'-biphenol-FT-IR and 1H NMR studies" @default.
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- W2016761798 doi "https://doi.org/10.1016/s0022-2860(97)00123-3" @default.
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