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- W2016763522 abstract "Durch Oxidation von Cu/In/V-Legierungen mit Sauerstoff konnten rotbraune Kristalle der neuen Verbindung CuInOVO4 (monoklin, P21/c, a = 879,3(2) pm, b = 615,42(6) pm, c = 1526,2(2) pm, β = 106,69(2)?, Z = 4) erhalten werden. Pseudomeroedrische Verzwillingung aller untersuchten Kristalle nach der (001)-Ebene täuschten aufgrund der speziellen Metrik der Elementarzelle die Raumgruppe C2221 vor. Die Struktur enthält isolierte Cu4O18-Einheiten, die aus trans-kantenverknüpften CuO6-Oktaedern aufgebaut sind. Sie werden durch in [010]-Richtung verlaufende [In4O16]-Bänder aus über Ecken und Kanten verknüpften InO6-Oktaedern zu Schichten parallel (001) verbunden. Die dreidimensionale Verknüpfung der Schichten erfolgt durch tetraedrische Vanadatgruppen. Die Struktur kann von einer verzerrten kubisch-dichtesten Packung der Sauerstoffatome abgeleitet werden, in der die Kupfer- und Indiumatome Oktaederlücken und die Vanadiumatome Tetraederlücken besetzen. CuInOVO4 – Single Crystals of a Copper(II) Indium Oxide Vanadate by Oxidation of Cu/In/V Alloys Red-brown crystals of the new compound CuInOVO4 (monoclinic, P21/c, a = 879.3(2) pm, b = 615.42(6) pm, c = 1526.2(2) pm, β = 106.69(2)?, Z = 4) were prepared by the reaction of Cu/In/V alloys with oxygen. The investigated crystals were twins by pseudo-merohedry with a (001) twinning plane. The structure contains isolated Cu4O18-groups consisting of trans edge sharing CuO6-octahedra. Interconnection of the groups by [In4O16]-ribbons running along [010] which are built of edge- and corner-sharing InO6-octahedra results in the formation of slabs perpendicular to the c-axis. The slabs are linked to a threedimensional framework by VO43– groups. The structure may be derived from a cubic closest packing of the oxygen atoms with copper and indium atoms in the octahedral and vanadium atoms in the tetrahedral vacancies." @default.
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- W2016763522 date "1999-05-01" @default.
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- W2016763522 title "CuInOVO4 - Einkristalle eines Kupfer(II)-indiumoxidvanadats durch Oxidation von Cu/In/V-Legierungen" @default.
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