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- W2016771284 abstract "In this paper we analyse the cathodoluminescence of cinnabar powder which emission appears as a broad band peaked at 1.65 eV at liquid helium temperature. In a previous paper we showed by kinetics measurements that this luminescence was due to a donor-acceptor pair emission mechanism. However the donor-acceptor model was not sufficient to explain the Gaussian shape of the emission band as well as its important width. We show here the influence of a strong phonon coupling by measurements in terms of temperature. Application of both donor-acceptor and vibronic models allows us to interpret this luminescence satisfactorily. We calculate the fundamental parameters of the emission (Bohr half-radius RB, maximum radiative probability WMAX, emission energy of the pairs at infinite separation hv∞). At the end a deconvolution method which takes into account the vibronic influence permits us to calculate the time-resolved spectra and to compare them with the experimental ones." @default.
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- W2016771284 date "1981-01-01" @default.
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- W2016771284 title "Experimental study and interpretation of the emission band situated at 1.65 eV in cinnabar" @default.
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- W2016771284 doi "https://doi.org/10.1016/0022-3697(81)90038-x" @default.
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