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- W2016774414 abstract "The electric-field $g$ shift of ${mathrm{Yb}}^{3+}$ in the scheelite series CaW${mathrm{O}}_{4}$, SrW${mathrm{O}}_{4}$, and BaW${mathrm{O}}_{4}$ has been measured. In SrW${mathrm{O}}_{4}$, and especially in BaW${mathrm{O}}_{4}$, the Yb ion is much smaller than the cation, and we find a substantial increase in the $g$ shifts, which indicates less restraint to ionic motion. The lattice restoring forces for loose ions are investigated through the use of the Born-Mayer theory of ionic bonding. We find that the predicted ionic $g$ shift is considerably larger than that observed. This may be due to substantial local distortion near a Yb impurity. Several other mechanisms for increasing the restoring forces on small ions are also considered." @default.
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- W2016774414 modified "2023-09-25" @default.
- W2016774414 title "Electric-Field-Induced<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>g</mml:mi></mml:math>Shifts for Loose Yb Ions in Three Scheelite Lattices" @default.
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- W2016774414 doi "https://doi.org/10.1103/physrevb.1.2935" @default.
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