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- W2016793949 abstract "Addition of the silicon-boron bonds of (dimethylphenylsilyl)boranes having pinacol, catechol, and diethylamino groups on the boron across carbon-carbon triple bonds is effectively catalyzed by palladium complexes. The silaboration of a variety of terminal alkynes took place with almost complete regio- and stereoselectivity to afford (Z)-1-boryl-2-silylalkenes in high yields. The silaboration products were subjected to the palladium-catalyzed cross-coupling reaction with aryl iodide and rhodium-catalyzed conjugate addition to methyl vinyl ketone, giving β-silylstyrene derivatives and δ-silyl-γ,δ-unsaturated ketones, respectively, in high yields." @default.
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- W2016793949 date "1999-07-01" @default.
- W2016793949 modified "2023-10-17" @default.
- W2016793949 title "Regio- and stereoselective synthesis of (Z)-β-silylalkenylboranes by silaboration of alkynes catalyzed by palladium and platinum complexes" @default.
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- W2016793949 doi "https://doi.org/10.1016/s0040-4020(99)00444-5" @default.
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