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- W2016807727 abstract "Saturation of the double bond in the non-reducing terminal unit of the tetrasaccharide amylase inhibitor, acarbose (1), with Raney nickel as the catalyst and at pH 8, gave 57% of a ∼1:1 mixture of the 5a-carba-gluco (2) and -ido (3) isomers together with cleavage products including 26% of the trisaccharide 6-deoxy-α-d-Glcp4N-(1→4)-α-d-Glcp-(1→4)-d-Glc (4). The saturated compounds were isolated and characterised using 1H- and 13C-n.m.r. spectroscopy. The preferred conformations of 1 and 2 were dependent on the state of ionisation of the bridging nitrogen atom. The inhibition of 1–4 of the hydrolysis of methyl β-maltoside by glucoamylase has been investigated; 1 and 2 were strong inhibitors." @default.
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- W2016807727 date "1991-12-01" @default.
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- W2016807727 title "Controlled reduction of acarbose: conformational analysis of acarbose and the resulting saturated products" @default.
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- W2016807727 doi "https://doi.org/10.1016/0008-6215(91)80045-o" @default.
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