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- W2016810921 abstract "Structures and magnetic properties for double perovskites Ba2CaMO6 (M=W, Re, Os) were investigated. Both Ba2CaReO6 and Ba2CaWO6 show structural phase transitions at low temperatures. For Ba2CaReO6, the second order transition from cubic Fm3¯m to tetragonal I4/m has been observed near 120 K. For Ba2CaWO6, the space group of the crystal structure is I4/m at 295 K and the transition to monoclinic I2/m has been observed between 220 K. Magnetic susceptibility measurements show that Ba2CaReO6 (S=1/2) and Ba2CaOsO6 (S=1) transform to an antiferromagnetic state below 15.4 and 51 K, respectively. Anomalies corresponding to their structural phase transition and magnetic transition have been also observed through specific heat measurements." @default.
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- W2016810921 date "2006-03-01" @default.
- W2016810921 modified "2023-09-26" @default.
- W2016810921 title "Structural phase transition and magnetic properties of double perovskites Ba2CaMO6 (M=W, Re, Os)" @default.
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- W2016810921 doi "https://doi.org/10.1016/j.jssc.2005.10.003" @default.
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