Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016845349> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2016845349 endingPage "430" @default.
- W2016845349 startingPage "421" @default.
- W2016845349 abstract "The pyrolysis of 1,4-dichlorobenzene (1,4-DCB) was carried out in sealed Pyrex ampoules under various conditions and with different additives. In the absence of additives, no products were formed below 380°C, but at 400°C, addition of HO· to the benzene ring of 1,4-DCB took place. The principal source of HO· was the interaction of pyrolyzed H· and ambient O2. At 500°C to 600°C, the principal reactions were chlorine transfer and biphenyl formation. At 500°C, in early stages of reaction, HO· reacted as before to produce chlorinated phenols, but in the later stages of reaction, dechlorination predominated. In the presence of Fe2O3, a potential electron acceptor, electron transfer reactions led to reduced metal ions, oxidized aromatic radicals, and halogen gas in the presence of O2. The principal thermal reaction observed at 200°C to 300°C was chlorine transfer. At a temperature around 380–400°C, increasing amounts of chlorinated phenoxy phenols suggested that reactions between oxygen and chlorinated benzene became important. At 500°C to 600°C, continuing dechlorination reactions led to biphenyl and triphenyl. With added FeS2, at 500°C, dechlorination occurred more efficiently than reactions with Fe2O3." @default.
- W2016845349 created "2016-06-24" @default.
- W2016845349 creator A5072420982 @default.
- W2016845349 creator A5083748416 @default.
- W2016845349 date "1994-07-01" @default.
- W2016845349 modified "2023-09-27" @default.
- W2016845349 title "Thermal transformations of 1,4-dichlorobenzene: effects of temperature, time and presence of iron species" @default.
- W2016845349 cites W1966425151 @default.
- W2016845349 cites W1966542889 @default.
- W2016845349 cites W1969368253 @default.
- W2016845349 cites W1981194878 @default.
- W2016845349 cites W1981697359 @default.
- W2016845349 cites W1982042418 @default.
- W2016845349 cites W1984687329 @default.
- W2016845349 cites W1995464187 @default.
- W2016845349 cites W2032782579 @default.
- W2016845349 cites W2034026168 @default.
- W2016845349 cites W2048341678 @default.
- W2016845349 cites W2077693265 @default.
- W2016845349 cites W2080149514 @default.
- W2016845349 cites W2081984770 @default.
- W2016845349 cites W2082473062 @default.
- W2016845349 cites W2094928295 @default.
- W2016845349 cites W2143720849 @default.
- W2016845349 cites W247965181 @default.
- W2016845349 cites W267670705 @default.
- W2016845349 doi "https://doi.org/10.1016/0045-6535(94)90116-3" @default.
- W2016845349 hasPublicationYear "1994" @default.
- W2016845349 type Work @default.
- W2016845349 sameAs 2016845349 @default.
- W2016845349 citedByCount "2" @default.
- W2016845349 countsByYear W20168453492022 @default.
- W2016845349 crossrefType "journal-article" @default.
- W2016845349 hasAuthorship W2016845349A5072420982 @default.
- W2016845349 hasAuthorship W2016845349A5083748416 @default.
- W2016845349 hasConcept C139066938 @default.
- W2016845349 hasConcept C178790620 @default.
- W2016845349 hasConcept C179104552 @default.
- W2016845349 hasConcept C185592680 @default.
- W2016845349 hasConcept C2777263448 @default.
- W2016845349 hasConcept C2777691172 @default.
- W2016845349 hasConcept C2777728882 @default.
- W2016845349 hasConcept C2780263894 @default.
- W2016845349 hasConcept C2780591471 @default.
- W2016845349 hasConcept C28845197 @default.
- W2016845349 hasConcept C36759035 @default.
- W2016845349 hasConcept C46062151 @default.
- W2016845349 hasConcept C505241676 @default.
- W2016845349 hasConcept C75473681 @default.
- W2016845349 hasConceptScore W2016845349C139066938 @default.
- W2016845349 hasConceptScore W2016845349C178790620 @default.
- W2016845349 hasConceptScore W2016845349C179104552 @default.
- W2016845349 hasConceptScore W2016845349C185592680 @default.
- W2016845349 hasConceptScore W2016845349C2777263448 @default.
- W2016845349 hasConceptScore W2016845349C2777691172 @default.
- W2016845349 hasConceptScore W2016845349C2777728882 @default.
- W2016845349 hasConceptScore W2016845349C2780263894 @default.
- W2016845349 hasConceptScore W2016845349C2780591471 @default.
- W2016845349 hasConceptScore W2016845349C28845197 @default.
- W2016845349 hasConceptScore W2016845349C36759035 @default.
- W2016845349 hasConceptScore W2016845349C46062151 @default.
- W2016845349 hasConceptScore W2016845349C505241676 @default.
- W2016845349 hasConceptScore W2016845349C75473681 @default.
- W2016845349 hasIssue "2" @default.
- W2016845349 hasLocation W20168453491 @default.
- W2016845349 hasOpenAccess W2016845349 @default.
- W2016845349 hasPrimaryLocation W20168453491 @default.
- W2016845349 hasRelatedWork W1980590990 @default.
- W2016845349 hasRelatedWork W2093121481 @default.
- W2016845349 hasRelatedWork W2132391739 @default.
- W2016845349 hasRelatedWork W241947395 @default.
- W2016845349 hasRelatedWork W301561681 @default.
- W2016845349 hasRelatedWork W3214006403 @default.
- W2016845349 hasRelatedWork W4244500733 @default.
- W2016845349 hasRelatedWork W4246933503 @default.
- W2016845349 hasRelatedWork W4252524260 @default.
- W2016845349 hasRelatedWork W938672060 @default.
- W2016845349 hasVolume "29" @default.
- W2016845349 isParatext "false" @default.
- W2016845349 isRetracted "false" @default.
- W2016845349 magId "2016845349" @default.
- W2016845349 workType "article" @default.