Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016861775> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2016861775 endingPage "963" @default.
- W2016861775 startingPage "956" @default.
- W2016861775 abstract "The heat capacity at constant pressure, Cp, of single-phase, face-centered cubic ScDx (x=1.75, 1.83, 1.91, and 1.99) was measured from room temperature to 950 K, and analyzed in terms of various contributions of the deuterium and metal constituents. Values ranged from approximately 40 to 80 J mol−1 K−1 with increasing temperature. The heat capacity at constant volume was assumed to be composed of lattice contributions from an acoustic vibrational mode, Cl(a)v, and an optical vibrational mode, Cl(o)v, plus an electronic contribution, Cev. The acoustic part, Cl(a)v, was evaluated as a Debye term with characteristic Debye temperatures calculated from measured values of temperature-dependent acoustic velocities and lattice constants. An isotope-adjusted Einstein temperature, derived from inelastic neutron scattering measurements on ScH2, was used to find Cl(o)v. The Cev term was evaluated from a published value of the electronic heat capacity constant for ScH2 (assumed to be the same for ScD2). Particular attention was paid to the dilation term, Cd=Cp−Cv, by evaluating it explicitly from the temperature-dependent volume expansion and elastic modulus. It was found that Cv=Cl(a)v+Cl(o) v+Cev+ΔC, the last term being an excess heat capacity of approximately the same magnitude as Cd. ΔC is attributed to anharmonic deuteron vibrations and deuteron–deuteron interactions, and is calculated for a specific model in reasonable agreement with the data." @default.
- W2016861775 created "2016-06-24" @default.
- W2016861775 creator A5065160796 @default.
- W2016861775 creator A5065342939 @default.
- W2016861775 creator A5085592400 @default.
- W2016861775 creator A5087164183 @default.
- W2016861775 creator A5089673814 @default.
- W2016861775 date "1986-01-15" @default.
- W2016861775 modified "2023-10-14" @default.
- W2016861775 title "Hydrogen contribution to the heat capacity of single phase, face centered cubic scandium deuteride" @default.
- W2016861775 cites W1997200396 @default.
- W2016861775 cites W2001755424 @default.
- W2016861775 cites W2013509130 @default.
- W2016861775 cites W2026277132 @default.
- W2016861775 cites W2026407893 @default.
- W2016861775 cites W2032565159 @default.
- W2016861775 cites W2036788872 @default.
- W2016861775 cites W2059883340 @default.
- W2016861775 cites W2065210575 @default.
- W2016861775 cites W2078531511 @default.
- W2016861775 cites W2086016648 @default.
- W2016861775 cites W2088201692 @default.
- W2016861775 cites W4246229304 @default.
- W2016861775 doi "https://doi.org/10.1063/1.450542" @default.
- W2016861775 hasPublicationYear "1986" @default.
- W2016861775 type Work @default.
- W2016861775 sameAs 2016861775 @default.
- W2016861775 citedByCount "7" @default.
- W2016861775 countsByYear W20168617752017 @default.
- W2016861775 crossrefType "journal-article" @default.
- W2016861775 hasAuthorship W2016861775A5065160796 @default.
- W2016861775 hasAuthorship W2016861775A5065342939 @default.
- W2016861775 hasAuthorship W2016861775A5085592400 @default.
- W2016861775 hasAuthorship W2016861775A5087164183 @default.
- W2016861775 hasAuthorship W2016861775A5089673814 @default.
- W2016861775 hasConcept C121332964 @default.
- W2016861775 hasConcept C147724859 @default.
- W2016861775 hasConcept C178790620 @default.
- W2016861775 hasConcept C184779094 @default.
- W2016861775 hasConcept C185592680 @default.
- W2016861775 hasConcept C25376523 @default.
- W2016861775 hasConcept C26873012 @default.
- W2016861775 hasConcept C40899509 @default.
- W2016861775 hasConcept C58364064 @default.
- W2016861775 hasConcept C60205243 @default.
- W2016861775 hasConcept C97355855 @default.
- W2016861775 hasConceptScore W2016861775C121332964 @default.
- W2016861775 hasConceptScore W2016861775C147724859 @default.
- W2016861775 hasConceptScore W2016861775C178790620 @default.
- W2016861775 hasConceptScore W2016861775C184779094 @default.
- W2016861775 hasConceptScore W2016861775C185592680 @default.
- W2016861775 hasConceptScore W2016861775C25376523 @default.
- W2016861775 hasConceptScore W2016861775C26873012 @default.
- W2016861775 hasConceptScore W2016861775C40899509 @default.
- W2016861775 hasConceptScore W2016861775C58364064 @default.
- W2016861775 hasConceptScore W2016861775C60205243 @default.
- W2016861775 hasConceptScore W2016861775C97355855 @default.
- W2016861775 hasIssue "2" @default.
- W2016861775 hasLocation W20168617751 @default.
- W2016861775 hasOpenAccess W2016861775 @default.
- W2016861775 hasPrimaryLocation W20168617751 @default.
- W2016861775 hasRelatedWork W1975609068 @default.
- W2016861775 hasRelatedWork W1996576805 @default.
- W2016861775 hasRelatedWork W2016438682 @default.
- W2016861775 hasRelatedWork W2036795784 @default.
- W2016861775 hasRelatedWork W2039923496 @default.
- W2016861775 hasRelatedWork W2057595885 @default.
- W2016861775 hasRelatedWork W2068457971 @default.
- W2016861775 hasRelatedWork W4245822443 @default.
- W2016861775 hasRelatedWork W4252934267 @default.
- W2016861775 hasRelatedWork W2128995884 @default.
- W2016861775 hasVolume "84" @default.
- W2016861775 isParatext "false" @default.
- W2016861775 isRetracted "false" @default.
- W2016861775 magId "2016861775" @default.
- W2016861775 workType "article" @default.