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- W2016867874 abstract "The near infrared spectra of the ionic complexes aniline(NH2)+–argon and aniline(ND2)+-argon have been measured by laser photodissociation spectroscopy. The bands observed from 10 500 to 13 500 cm−1 have been assigned to the D1(A∼2A2)←D0(X∼2B1) electronic transition within the solvated chromophore. They are characterized by a long vibrational progression involving the 6a mode. On the basis of CASSCF calculations, a large change of geometry along this coordinate is found while the amino group remains in the ring plane. Therefore, a change of the conjugation of the ring rather than a charge transfer is inferred. This is thought to be the origin of the extent of the progression." @default.
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- W2016867874 date "2006-02-01" @default.
- W2016867874 modified "2023-10-07" @default.
- W2016867874 title "Near infrared photodissociation spectra of the aniline+–argon ionic complexes" @default.
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- W2016867874 doi "https://doi.org/10.1016/j.cplett.2005.11.089" @default.
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