Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016876144> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2016876144 endingPage "1105" @default.
- W2016876144 startingPage "1103" @default.
- W2016876144 abstract "The relative basicity order of ammonia, pyridine, aniline and N-methyl-, N,N-dimethyl-, N-ethyl-, N,N-diethyl-, N-aryl- and N,N-diaryl-substituted anilines have been determined potentiometrically with perchloric acid in nitrobenzene solvent and found to be NH3 > Py > PhNEt2 > PhNMe2 > PhNHEt > PhNHMe > PhNH2 > Ph2NH > Ph3N. This order in general conflicts with the results observed by other workers in either the gas phase or in the condensed phase. N-Alkyl substitution increases the basicity of the aniline, and N-aryl substitution decreases its basicity. Moreover, the number and size of the substituent influence the basicity of aniline. N-Ethyl-substituted anilines are more basic than the corresponding N-methyl-substituted anilines. The position of pyridine in the order is surprising and difficult to interpret." @default.
- W2016876144 created "2016-06-24" @default.
- W2016876144 creator A5021784462 @default.
- W2016876144 creator A5023242849 @default.
- W2016876144 creator A5042845062 @default.
- W2016876144 creator A5044970011 @default.
- W2016876144 date "1986-01-01" @default.
- W2016876144 modified "2023-10-18" @default.
- W2016876144 title "Titrations in non-aqueous media. Part III. Basicity order of aniline, N-Alkyl- and N-aryl-substituted anilines and pyridine in nitrobenzene solvent" @default.
- W2016876144 doi "https://doi.org/10.1039/an9861101103" @default.
- W2016876144 hasPublicationYear "1986" @default.
- W2016876144 type Work @default.
- W2016876144 sameAs 2016876144 @default.
- W2016876144 citedByCount "8" @default.
- W2016876144 countsByYear W20168761442019 @default.
- W2016876144 crossrefType "journal-article" @default.
- W2016876144 hasAuthorship W2016876144A5021784462 @default.
- W2016876144 hasAuthorship W2016876144A5023242849 @default.
- W2016876144 hasAuthorship W2016876144A5042845062 @default.
- W2016876144 hasAuthorship W2016876144A5044970011 @default.
- W2016876144 hasConcept C145148216 @default.
- W2016876144 hasConcept C155647269 @default.
- W2016876144 hasConcept C161790260 @default.
- W2016876144 hasConcept C178790620 @default.
- W2016876144 hasConcept C179104552 @default.
- W2016876144 hasConcept C184866935 @default.
- W2016876144 hasConcept C185592680 @default.
- W2016876144 hasConcept C2776793192 @default.
- W2016876144 hasConcept C2778161354 @default.
- W2016876144 hasConcept C2778689049 @default.
- W2016876144 hasConcept C2779244968 @default.
- W2016876144 hasConcept C2779485729 @default.
- W2016876144 hasConcept C2780263894 @default.
- W2016876144 hasConcept C2780471494 @default.
- W2016876144 hasConcept C2780709120 @default.
- W2016876144 hasConcept C2780809723 @default.
- W2016876144 hasConcept C2781076698 @default.
- W2016876144 hasConceptScore W2016876144C145148216 @default.
- W2016876144 hasConceptScore W2016876144C155647269 @default.
- W2016876144 hasConceptScore W2016876144C161790260 @default.
- W2016876144 hasConceptScore W2016876144C178790620 @default.
- W2016876144 hasConceptScore W2016876144C179104552 @default.
- W2016876144 hasConceptScore W2016876144C184866935 @default.
- W2016876144 hasConceptScore W2016876144C185592680 @default.
- W2016876144 hasConceptScore W2016876144C2776793192 @default.
- W2016876144 hasConceptScore W2016876144C2778161354 @default.
- W2016876144 hasConceptScore W2016876144C2778689049 @default.
- W2016876144 hasConceptScore W2016876144C2779244968 @default.
- W2016876144 hasConceptScore W2016876144C2779485729 @default.
- W2016876144 hasConceptScore W2016876144C2780263894 @default.
- W2016876144 hasConceptScore W2016876144C2780471494 @default.
- W2016876144 hasConceptScore W2016876144C2780709120 @default.
- W2016876144 hasConceptScore W2016876144C2780809723 @default.
- W2016876144 hasConceptScore W2016876144C2781076698 @default.
- W2016876144 hasIssue "9" @default.
- W2016876144 hasLocation W20168761441 @default.
- W2016876144 hasOpenAccess W2016876144 @default.
- W2016876144 hasPrimaryLocation W20168761441 @default.
- W2016876144 hasRelatedWork W1970813347 @default.
- W2016876144 hasRelatedWork W1984744703 @default.
- W2016876144 hasRelatedWork W1985348508 @default.
- W2016876144 hasRelatedWork W2002140408 @default.
- W2016876144 hasRelatedWork W2004784739 @default.
- W2016876144 hasRelatedWork W2016876144 @default.
- W2016876144 hasRelatedWork W2040725950 @default.
- W2016876144 hasRelatedWork W2324898221 @default.
- W2016876144 hasRelatedWork W2950354789 @default.
- W2016876144 hasRelatedWork W2951766199 @default.
- W2016876144 hasVolume "111" @default.
- W2016876144 isParatext "false" @default.
- W2016876144 isRetracted "false" @default.
- W2016876144 magId "2016876144" @default.
- W2016876144 workType "article" @default.