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- W2016945385 abstract "Abstract 4-[4- 2 H]Aminobutyrate was prepared by incubation in 2 H 2 O of glutamate with a partially purified glutamate decarboxylase from mouse brain. The 4 R configuration was assigned to the compound on the basis of 1 H nmr analysis of the ω-camphanoylamide of its methyl ester in the presence of Eu(dpm) 3 . Moreover 4-[4( S )4- 3 H,U- 14 C]aminobutyrate was shown to be formed from [2( S )2- 3 H,U- 14 C]glutamate by the same enzyme fraction. It is therefore demonstrated that glutamate decarboxylation catalyzed by this enzyme preparation occurs with retention of configuration." @default.
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- W2016945385 date "1980-12-01" @default.
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- W2016945385 title "Stereochemical action of mouse brain glutamate decarboxylase" @default.
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