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- W2016990060 abstract "Combined thermal analysis was used to establish the dissociation steps for the hydrated oxalates of calcium and magnesium. While dehydration of calcium oxalate monohydrate is governed by three-dimensional phase boundary movement, dehydration of magnesium oxalate is governed by Avrami—Erofeev nuclei growth. Both dehydration reactions demonstrated that the activation energy and the pre-exponential factor vary with temperature over wide ranges. Accordingly, the methods of Reich and Kissinger (based on the maximum rate temperature) or Carroll and Manche are not suitable. Moreover they could not distinguish between the overlapping reactions or mechanisms. They can be only used as a guide in differentiating between the possible mechanisms obtained using the methods of Coats and Redfern or Šatava and Škvàra. The latter method is recommended since it gives a smaller number of possible operating mechanisms. When possible mechanisms have close activation energies both techniques are needed. Both anhydrous oxalates dissociated to the carbonates according to the Avrami—Erofeev nuclei growth, A2. For the magnesium salt, at low heating rates, this step was accompanied by dissociation of MgCO3 to MgO. Both carbonates dissociate according to a three-dimensional phase boundary migration mechanism." @default.
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- W2016990060 date "1984-01-01" @default.
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- W2016990060 title "Kinetics of the decomposition of hydrated oxalates of calcium and magnesium in air" @default.
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- W2016990060 doi "https://doi.org/10.1016/0040-6031(84)80027-1" @default.
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