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- W2017000434 abstract "In comprison with the previous structural study [Anulewicz et al. (1991). Pol. J. Chem. 65, 465–471], for which only the coordinates of all non-H atoms and of some H atoms were reported, the current redetermination of the title compound, C13H10Br2N2, additionally reports anisotropic displacement parameters for all non-H atoms and the coordinates of all H atoms, accompanied by higher accuracy of the geometric parameters. Two independent half-molecules are present in the asymmetric unit, which are completed by a twofold rotation axis as symmetry element. In the crystal, intermolecular N—H⋯N hydrogen bonds link the molecules into dimers. Linear chains parallel to [102] are formed by intermolecular Br⋯Br interactions of 3.4328 (7) Å between two Br atoms of adjacent molecules. The dihedral angles between the benzene rings are 50.05 (15) and 75.61 (11)° in the two independent molecules. Owing to the twofold symmetry of the molecules, H atoms attached to the N atoms are only half-occupied, leading to them being disordered over two positions of equal occupancy." @default.
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- W2017000434 date "2011-04-16" @default.
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- W2017000434 title "Redetermination of (<i>E</i>)-<i>N</i>,<i>N</i>′-bis(4-bromophenyl)formamidine" @default.
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- W2017000434 doi "https://doi.org/10.1107/s1600536811013419" @default.
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