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- W2017010453 abstract "We report on the existence in the U–Ru–Al system of a novel compound, URu2Al10, crystallizing in the orthorhombic YbFe2Al10-type structure, where the uranium atoms are caged in Ru–Al polyhedra, forming a clathrate-like structure. Results of the magnetic susceptibility, electrical resistivity in zero and in magnetic fields up to 8 T, thermopower and specific heat, performed in a wide temperature range, are presented. No magnetically ordered state down to the lowest temperature measured has been found. On the basis of (i) the susceptibility anomaly occurring at about 50 K and (ii) the positive magnetoresistivity, growing with applied magnetic field as αBn (n ≈ 3/2), (iii) a characteristic temperature variation of the thermopower, as well as (iv) a moderate value of the Sommerfeld coefficient, a mixed-valence state of uranium in this compound has been postulated. This points to similarities between the presently studied compound and the behaviour of other Ru-containing uranium ternaries, such as U2Ru2Sn and U2RuGa8, classified earlier as valence-fluctuating type materials." @default.
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- W2017010453 date "2011-07-01" @default.
- W2017010453 modified "2023-10-18" @default.
- W2017010453 title "Crystal structure and physical properties of a new intermetallic compound URu2Al10" @default.
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- W2017010453 doi "https://doi.org/10.1016/j.intermet.2011.02.008" @default.
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