Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017014457> ?p ?o ?g. }
- W2017014457 endingPage "3002" @default.
- W2017014457 startingPage "2995" @default.
- W2017014457 abstract "Both C(2)-P bond breaking and formation in the S-C-P(+) system do not occur according to the antiperiplanar lone pair hypothesis. Experiments using 2-phosphonio derivatives of 5-tert-butyl-1,3-dithiane and cis-4,6-dimethyl-1,3-dithiane are against the participation of higher-energy boat conformers as reactive intermediates. The results obtained support a possibility of conformational adjustment in the course of the reaction. Stereoelectronic control of the C(2)-P bond breaking and formation results from interplay of several factors. The role of the n(S)-sigma(C(2))(-)(P) and sigma(C(4,6))(-)(S)-sigma(C(2))(-)(P) hyperconjugation, as well as of the repulsive interactions between lone electron pairs pi(S) of endocyclic sulfur atoms and pi-electrons of the phenyl ring(s) connected with phosphorus, is discussed." @default.
- W2017014457 created "2016-06-24" @default.
- W2017014457 creator A5012568397 @default.
- W2017014457 creator A5036609614 @default.
- W2017014457 date "1996-01-01" @default.
- W2017014457 modified "2023-10-18" @default.
- W2017014457 title "Inapplicability of the Antiperiplanar Lone Pair Hypothesis to C−P Bond Breaking and Formation in Some S−C−P+Systems" @default.
- W2017014457 cites W1967634737 @default.
- W2017014457 cites W1968555299 @default.
- W2017014457 cites W1973079275 @default.
- W2017014457 cites W1973248270 @default.
- W2017014457 cites W1974157889 @default.
- W2017014457 cites W1975457309 @default.
- W2017014457 cites W1976066092 @default.
- W2017014457 cites W1977848164 @default.
- W2017014457 cites W1980855716 @default.
- W2017014457 cites W1991716990 @default.
- W2017014457 cites W1991847724 @default.
- W2017014457 cites W1994969703 @default.
- W2017014457 cites W1996973796 @default.
- W2017014457 cites W1997855169 @default.
- W2017014457 cites W1998633267 @default.
- W2017014457 cites W2005540985 @default.
- W2017014457 cites W2007330836 @default.
- W2017014457 cites W2015431136 @default.
- W2017014457 cites W2025431101 @default.
- W2017014457 cites W2030286780 @default.
- W2017014457 cites W2033443478 @default.
- W2017014457 cites W2034848039 @default.
- W2017014457 cites W2035542702 @default.
- W2017014457 cites W2044000088 @default.
- W2017014457 cites W2051032200 @default.
- W2017014457 cites W2051646816 @default.
- W2017014457 cites W2056142042 @default.
- W2017014457 cites W2057017092 @default.
- W2017014457 cites W2058638525 @default.
- W2017014457 cites W2064104387 @default.
- W2017014457 cites W2065619311 @default.
- W2017014457 cites W2066142636 @default.
- W2017014457 cites W2066708437 @default.
- W2017014457 cites W2067880138 @default.
- W2017014457 cites W2068021398 @default.
- W2017014457 cites W2069692371 @default.
- W2017014457 cites W2070175773 @default.
- W2017014457 cites W2071814218 @default.
- W2017014457 cites W2079747661 @default.
- W2017014457 cites W2083974435 @default.
- W2017014457 cites W2090388252 @default.
- W2017014457 cites W2093082790 @default.
- W2017014457 cites W2118402785 @default.
- W2017014457 cites W2121424262 @default.
- W2017014457 cites W2198371282 @default.
- W2017014457 cites W2949167925 @default.
- W2017014457 cites W2949719253 @default.
- W2017014457 cites W2950007886 @default.
- W2017014457 cites W2950469006 @default.
- W2017014457 cites W2950953675 @default.
- W2017014457 cites W2952309462 @default.
- W2017014457 cites W3005162047 @default.
- W2017014457 doi "https://doi.org/10.1021/jo941771m" @default.
- W2017014457 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11667160" @default.
- W2017014457 hasPublicationYear "1996" @default.
- W2017014457 type Work @default.
- W2017014457 sameAs 2017014457 @default.
- W2017014457 citedByCount "7" @default.
- W2017014457 countsByYear W20170144572018 @default.
- W2017014457 countsByYear W20170144572019 @default.
- W2017014457 crossrefType "journal-article" @default.
- W2017014457 hasAuthorship W2017014457A5012568397 @default.
- W2017014457 hasAuthorship W2017014457A5036609614 @default.
- W2017014457 hasConcept C115624301 @default.
- W2017014457 hasConcept C155518411 @default.
- W2017014457 hasConcept C155647269 @default.
- W2017014457 hasConcept C177186529 @default.
- W2017014457 hasConcept C178790620 @default.
- W2017014457 hasConcept C185592680 @default.
- W2017014457 hasConcept C18705241 @default.
- W2017014457 hasConcept C2780378348 @default.
- W2017014457 hasConcept C32909587 @default.
- W2017014457 hasConcept C46000676 @default.
- W2017014457 hasConcept C71240020 @default.
- W2017014457 hasConcept C77758465 @default.
- W2017014457 hasConcept C8010536 @default.
- W2017014457 hasConceptScore W2017014457C115624301 @default.
- W2017014457 hasConceptScore W2017014457C155518411 @default.
- W2017014457 hasConceptScore W2017014457C155647269 @default.
- W2017014457 hasConceptScore W2017014457C177186529 @default.
- W2017014457 hasConceptScore W2017014457C178790620 @default.
- W2017014457 hasConceptScore W2017014457C185592680 @default.
- W2017014457 hasConceptScore W2017014457C18705241 @default.
- W2017014457 hasConceptScore W2017014457C2780378348 @default.
- W2017014457 hasConceptScore W2017014457C32909587 @default.
- W2017014457 hasConceptScore W2017014457C46000676 @default.
- W2017014457 hasConceptScore W2017014457C71240020 @default.
- W2017014457 hasConceptScore W2017014457C77758465 @default.
- W2017014457 hasConceptScore W2017014457C8010536 @default.
- W2017014457 hasIssue "9" @default.
- W2017014457 hasLocation W20170144571 @default.