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- W2017014725 abstract "In aerobic conditions, (η5-C5H5)Rh(CO)2 reacts with diphenylphosphine to give the phosphido complex [Rh(O2)(PHPh2)3PPh2]; under a dinitrogen atmosphere, the same reaction gave [Rh(PHPh2)PPh2]3. A possible scheme for these reactions is proposed. The complex [Rh(O2)(PHPh2)3PPh2] reacts with halogens or CH3I giving the corresponding halogen derivatives [Rh(O2)(PHPh2)3X] (X = Cl, Br, I)." @default.
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- W2017014725 date "1977-06-01" @default.
- W2017014725 modified "2023-10-16" @default.
- W2017014725 title "Phosphido complexes obtained by reaction of (η5-C5H5)Rh(CO)2 with diphenylphosphine. A determining role of dioxygen on the nature of the products" @default.
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- W2017014725 doi "https://doi.org/10.1016/s0022-328x(00)98122-1" @default.
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