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- W2017016484 abstract "Reactions of 1,1′-(1,3-propylene)bis-1H-benzotriazole (pbbt) and KSCN with Ni(II) or Co(II) salt lead to the formation of two new double helix chain coordination polymers {[Ni(pbbt)2(NCS)2]·H2O}n 1 and {[Co(pbbt)2(NCS)2]·H2O}n 2. Their third-order nonlinear optical (NLO) properties were determined with a 7 ns pulsed laser at 532 nm. The results show that polymer 2 exhibits large NLO absorptive effects (α2 = 1.4 × 10−9 m W−1), and both of them show strong NLO refractive behaviors with the refractive index n2 of 3.02 × 10−18 m2 W−1 for 1 and 8.23 × 10−18 m2 W−1 for 2. The hyperpolarizability |γ| values of 1 and 2 were calculated to be 1.68 × 10−29 esu and 4.58 × 10−29 esu, respectively. This indicates that the third-order NLO properties of coordination polymers can be altered through metal ions manipulation." @default.
- W2017016484 created "2016-06-24" @default.
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- W2017016484 date "2008-11-01" @default.
- W2017016484 modified "2023-10-17" @default.
- W2017016484 title "Double helix chain frameworks constructed from bis-benzotriazole building blocks: Syntheses, crystal structures and third-order nonlinear optical properties" @default.
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- W2017016484 doi "https://doi.org/10.1016/j.molstruc.2008.03.058" @default.
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