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- W2017016549 abstract "31P and 195Pt cross-polarization magic-angle spinning nuclear magnetic resonance (CP-MAS NMR) spectra of three platinum complexes of formal oxidation state Pt(0) and Pt(II), respectively, are reported. All three complexes, (Ph3P)2Pt(C2H4) (1), (Et2PCH2CH2PEt2)Pt(CCH)2 (2) and (Ph2PCH2CH2 PPh2)Pt(CCC(CH3) CH2)2 (3) contain the square-planar cis-P2PtC2 fragment and show unusual NMR spectroscopic properties insofar that the 195Pt shielding patterns are fairly narrow in relation to what one would generally have to expect for 195Pt in square-planar coordination. Another unexpected NMR property of the cis-P2PtC2 fragment in 1–3 is the absence of spinning frequency-dependent second-order effects in this solid-state ABX spin system." @default.
- W2017016549 created "2016-06-24" @default.
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- W2017016549 date "1995-01-01" @default.
- W2017016549 modified "2023-09-27" @default.
- W2017016549 title "Cross-polarization magic-angle spinning nuclear magnetic resonance study of platinum complexes containing the cis-P2PtC2 fragment" @default.
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- W2017016549 doi "https://doi.org/10.1016/0926-2040(94)00032-8" @default.
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