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- W2017018760 abstract "Products were determined from reaction of biphenyl-2-thiol (5) with methanol in a packed flow reactor at elevated temperatures and ca. atmospheric pressure. At 450–550° thermolysis of 5 gives small yields of dibenzothiophene (1) and biphenyl (2). With sulfided alumina, products vary with reaction temperature from 82% S-methyl-5 at 250° to only 1 plus 2 at 550°. At 450° with sulfided cobaltous oxide-molybdic oxide-aluminum oxide (CMA-1), 5 and its isomers give mainly desulfurization to 2 (81%), plus C-melhylalion to melhylbiphenyls and fluorene. With CMA-1 at 450° the arrays of products from 1 and 5 are closely similar." @default.
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- W2017018760 date "1978-03-01" @default.
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- W2017018760 title "The insertion and extrusion of heterosulfur bridges. VI. Comparative desulfurizations of dibenzothiophene and biphenylthiols" @default.
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- W2017018760 doi "https://doi.org/10.1002/jhet.5570150219" @default.
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