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- W2017030268 abstract "We introduce an approach for the synthesis of networks based on the coordination of alkyl-substituted cucurbit[5]uril (SQ[5]), dimethylcucurbit[5]uril (DMeQ[5]), 1,3-dicyclohexanocucurbit[5]uril (1,3-DCyHQ[5]), 1,2,4-tricyclohexanocucurbit[5]uril (1,2,4-TriCyHQ[5]), 1,2,3-cyclohexanocucurbit[5]uril (1,2,3-TriCyHQ[5]), and pentacyclopentanocucurbit[5]uril (PCyPQ[5]) with K+ ions in the absence of a structure inducer. These novel SQ[5]-K+-based networks feature trigonal-planar branches constructed from three SQ[5]s and K+ ions in a triangular manner, in which the coordination of each K+ ion to the five portal carbonyl oxygen atoms of one SQ[5] as well as to a bridging portal carbonyl oxygen from an adjacent SQ[5] draws the edges of three portals into close proximity. Thus, a 3-K+-cation junction is formed at each portal of the S[5] and there are four 3-K+-cation junctions in which one or two coordinated water molecule(s) are shared by the three K+ cations in the trigonal-planar branch. Detailed inspection of the relationship of the planes at the 3-K+ junction has revealed that the dihedral angles between the junction plane and the center junction plane have a strong influence on the supramolecular assembly of SQ[5] with K+ ions into 2D-networks or 3D-frameworks. Moreover, these dihedral angles determine the structural conformation of the SQ[5]-K+-based networks and the superimposition of 2D-networks in the compounds." @default.
- W2017030268 created "2016-06-24" @default.
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- W2017030268 date "2013-01-01" @default.
- W2017030268 modified "2023-10-09" @default.
- W2017030268 title "An approach to networks based on coordination of alkyl-substituted cucurbit[5]urils and potassium ions" @default.
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- W2017030268 doi "https://doi.org/10.1039/c3ce26491b" @default.
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