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- W2017033483 abstract "Abstract The stereochemistry of reaction of some optically active organosilanes R 3 Si✩-X with a representative series of p -substituted aryloxides and allyllithium emphasizes the relative influence of the attacking anion. For a given leaving group, the stereochemistry essentially depends upon the electronic character of p -substituents and the iron-pair dissociation of the aryloxides. This dependence is also supported by the stereochemical behavior of allyllithium. A simple mechanistic interpretation of the data is proposed, based on a description of nucleophilic substitutions at silicon as a frontier-orbitals process." @default.
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- W2017033483 title "Nucleophilic substitution at silicon: influence of the attacking allyllithium and aryloxide anion on the stereochemistry and a simple mechanistic proposal" @default.
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- W2017033483 doi "https://doi.org/10.1016/s0022-328x(00)86817-5" @default.
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