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- W2017033765 abstract "The demonstration experiment describes the isolation of [Co(H2O)6]3+ both as the pure blue crystalline cesium cobalt alum, CsCo(SO4)2·12H2O, and as a light greenish-blue solid solution of ammonium cobalt alum in (NH4)Al(SO4)2·12H2O. The hexaaquacobalt(III) ion is prepared chemically by oxidation with hydrogen peroxide, taking advantage of the stabilization of CoIII relative to CoII by complexation with the carbonate ligand. A brief description of alum structure and a characterization of alum subclasses are included." @default.
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- W2017033765 date "2002-08-01" @default.
- W2017033765 modified "2023-09-25" @default.
- W2017033765 title "Cobalt alums. A demonstration experiment" @default.
- W2017033765 doi "https://doi.org/10.1021/ed079p958" @default.
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