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• W2017033968 abstract "A new synthesis of fluorinated pyrazoles, a class of compounds with potential in medicinal chemistry, is described. The treatment of benzoylfluoroacetonitrile with hydrazine yielded the expected new 3-amino-4-fluoropyrazole, while the analogous reaction of α-cyano-α,α-difluoroketones with hydrazine in refluxing isopropanol surprisingly gave rise to 3-unsubstituted 4-fluoropyrazoles via an unprecedented mechanism. The isolation of intermediate hydrazine adducts led to a mechanistic rationale for this transformation." @default.
• W2017033968 created "2016-06-24" @default.
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• W2017033968 date "2010-09-15" @default.
• W2017033968 modified "2023-10-08" @default.
• W2017033968 title "New Synthesis of Fluorinated Pyrazoles" @default.
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• W2017033968 doi "https://doi.org/10.1021/ol1019713" @default.
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