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- W2017046212 abstract "A general method for the synthesis of pyrimidine N-oxides from the appropriate carboxamide oximes is described. The conversion involves a treatment of various carboxamide oximes with either 1,1,3,3-tetramethoxypropane, 2,4-pentanedione, 3-ethoxy-2-propenal, 4,4-dimethoxy-2-butanone or 4-methoxy-3-butene-2-one in the presence of trifluoroacetic acid as a catalyst. The application of an unsymmetrical dicarbonyl compound leads exclusively to one product. Our approach is a method of choice for the preparation of pyridylpyrimidine N-oxides." @default.
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- W2017046212 date "1998-04-01" @default.
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- W2017046212 title "Carboxamide oximes as convenient precursors for the synthesis of pyrimidine N-oxides" @default.
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- W2017046212 doi "https://doi.org/10.1016/s0040-4020(98)00152-5" @default.
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