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- W2017051221 abstract "Abstract With the goal of achieving effective ethylene/ethane separation, we evaluated the gas sorption properties of four pillared‐layer‐type porous coordination polymers with double interpenetration, [Zn 2 (tp) 2 (bpy)] n ( 1 ), [Zn 2 (fm) 2 (bpe)] n ( 2 ), [Zn 2 (fm) 2 (bpa)] n ( 3 ), and [Zn 2 (fm) 2 (bpy)] n ( 4 ) (tp=terephthalate, bpy=4,4′‐bipyridyl, fm=fumarate, bpe=1,2‐di(4‐pyridyl)ethylene and bpa=1,2‐di(4‐pyridyl)ethane). It was found that 4 , which contains the narrowest pores of all of these compounds, exhibited ethylene‐selective sorption profiles. The ethylene selectivity of 4 was estimated to be 4.6 at 298 K based on breakthrough experiments using ethylene/ethane gas mixtures. In addition, 4 exhibited a good regeneration ability compared with a conventional porous material." @default.
- W2017051221 created "2016-06-24" @default.
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- W2017051221 date "2014-04-01" @default.
- W2017051221 modified "2023-10-18" @default.
- W2017051221 title "Structural Optimization of Interpenetrated Pillared-Layer Coordination Polymers for Ethylene/Ethane Separation" @default.
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- W2017051221 doi "https://doi.org/10.1002/asia.201400122" @default.
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