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- W2017051285 abstract "The biomimetic formation of gramicidin S, cyclo(-d-Phe-Pro-Val-Orn-Leu-)2, by the dimerization and cyclization of pentapeptide precursor without the protection of δ-amino group of the Orn residue was examined on a solid support. The cyclization of H-d-Phe-Pro-Val-Orn-Leu-oxime on a resin with an oxime group of 0.62 mmol/g in 1,4-dioxane directly gave gramicidin S in a 50% yield. The dimerization–cyclization mode on the solid support was similar to that of the biosynthesis of gramicidin S on an enzyme." @default.
- W2017051285 created "2016-06-24" @default.
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- W2017051285 date "2006-11-01" @default.
- W2017051285 modified "2023-09-30" @default.
- W2017051285 title "Biomimetic formation of gramicidin S by dimerization–cyclization of pentapeptide precursor on solid support" @default.
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- W2017051285 doi "https://doi.org/10.1016/j.tetlet.2006.09.146" @default.
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