Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017064990> ?p ?o ?g. }
- W2017064990 abstract "Capillary filling dynamics of liquid $n$-tetracosane ($nmathrm{text{ensuremath{-}}}{mathrm{C}}_{24}{mathrm{H}}_{50}$) in a network of cylindrical pores with 7 and 10 nm mean diameter in monolithic silica glass (Vycor) exhibit an abrupt temperature-slope change at ${T}_{s}=54text{ }ifmmode^circelsetextdegreefi{}mathrm{C}$, $ensuremath{sim}4text{ }ifmmode^circelsetextdegreefi{}mathrm{C}$ above bulk and $ensuremath{sim}16text{ }ifmmode^circelsetextdegreefi{}mathrm{C}$, $8text{ }ifmmode^circelsetextdegreefi{}mathrm{C}$, respectively, above pore freezing. It can be traced to a sudden inversion of the surface tension's $T$ slope, and thus to a decrease in surface entropy at the advancing pore menisci, characteristic of the formation of a single solid monolayer of rectified molecules, known as surface freezing from macroscopic, quiescent tetracosane melts. The imbibition speeds, that are the squared prefactors of the observed square-root-of-time Lucas-Washburn invasion kinetics, indicate a conserved bulk fluidity and capillarity of the nanopore-confined liquid, if we assume a flat lying, sticky hydrocarbon backbone monolayer at the silica walls." @default.
- W2017064990 created "2016-06-24" @default.
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- W2017064990 date "2009-10-20" @default.
- W2017064990 modified "2023-10-18" @default.
- W2017064990 title "Spontaneous Imbibition Dynamics of an<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>n</mml:mi></mml:math>-Alkane in Nanopores: Evidence of Meniscus Freezing and Monolayer Sticking" @default.
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- W2017064990 doi "https://doi.org/10.1103/physrevlett.103.174501" @default.
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