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- W2017080026 abstract "The compounds (HB(Me{sub 2}pz){sub 3})MoO(S{sub 2}P(OEt){sub 2}) (1a) and (HB(Me{sub 2}pz){sub 3})MoO{sub 2}(S{sub 2}P(OEt){sub 2}(2)) containing bidentate and monodentate S{sub 2}P (OEt){sub 2}-ligands, respectively, have been prepared by the reaction of Mo{sub 2}O{sub 3}(S{sub 2}P(OEt){sub 2}){sub 4} with K(HB(Me{sub 2}pz){sub 3}). (HB(Me{sub 2}pz){sub 3})MoO(S{sub 2}P(OEt){sub 2}) and its analog (HB(Me{sub 2}pz){sub 3})MoO(S{sub 2}P(OMe){sub 2}) have also been prepared in higher yield by the reaction of MoO{sub 2}O{sub 3}(S{sub 2}(OEt){sub 2}){sub 4} with Ph{sub 3}P followed by the reaction with K(HB(Me{sub 2}pz){sub 3}). Both 1a and 2 have been structurally characterized by x-ray crystallography, and the crystallographic data are presented. The molecular structures were also determined. Compound 1a reduces Me{sub 2}SO to Me{sub 2}S. The kinetic data and activation parameters are presented for this reaction. Compound 2 oxidizes Ph{sub 3}P to Ph{sub 3}PO. Both complexes catalyze the oxidation of Ph{sub 3}P by Me{sub 2}SO. 34 references, 4 figures, 5 tables." @default.
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- W2017080026 title "Synthesis, characterization, and oxygen atom transfer reactions of {HB(Me2C3N2H)3}MoO{S2P(OR)2} and {HB(Me2C3N2H)3}MoO2{.eta.1-S2P(OEt)2}" @default.
- W2017080026 doi "https://doi.org/10.1021/ic00290a029" @default.
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