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- W2017109384 abstract "The thermal isomerization of bicyclo[2,1,1]hex-2-ene to bicyclo[3,1,0]hex-2-ene has been investigated in the gas phase in the temperature range 149–190 °C. In an aged reaction vessel the reaction is homogeneous, of the first order, and the rate constant is independent of pressure down to 0·5 Torr. The rate constants fit the Arrhenius equation (i)(where R= 1·987 cal. deg.–1 mole–1). A consideration of these Arrhenius parameters leads to the conclusion that the isomerization is a concerted process. It is however likely that some substituted bicyclo-[2,1,1]hex-2-enes will isomerize by a two-step process involving a biradical intermediate. k= 1013·95 ± 0·07 exp (–35,170 ± 140/RT) sec.–1(i)" @default.
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- W2017109384 date "1970-01-01" @default.
- W2017109384 modified "2023-09-25" @default.
- W2017109384 title "The thermal isomerization of bicyclo[2,1,1]hex-2-ene and tricyclo[3,3,0,02,6]oct-3-ene" @default.
- W2017109384 doi "https://doi.org/10.1039/j29700001410" @default.
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