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- W2017110815 abstract "Magnetic and thermoelectric properties of Nd1−xCaxBaCo2O5.5 and Nd1−xCaxCoO3 have been studied. Ca doping in Nd1−xCaxBaCo2O5.5 (x ≤ 0.2) preserves the metal to insulator transition (MIT) at 340–360 K. While the antiferromagnetic state disappears upon doping, the Curie temperature is increasing and becomes close to MIT for x > 0.12. The magnetic susceptibility of Nd1−xCaxCoO3 is paramagnetic for x up to 0.2, similar to the parent compound, with some indication of cluster-glass-like behavior at temperatures below 30 K. The increasing effective paramagnetic moments with doping suggest a low spin state of Co3+ and a high spin state of Co4+. Maximum observed ZT reaches a value close to 0.2 for x = 0.15 at 800 K, which is one of the highest values for perovskite cobaltites." @default.
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- W2017110815 date "2012-04-01" @default.
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- W2017110815 title "Comparison of magnetic and thermoelectric properties of (Nd,Ca)BaCo<sub>2</sub>O<sub>5.5</sub> and (Nd,Ca)CoO<sub>3</sub>" @default.
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- W2017110815 doi "https://doi.org/10.1063/1.3679561" @default.
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