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- W2017111908 abstract "Group IB metal salts solubilized in alkylpolyamine solvents have been found to catalyze the homogeneous hydrogenation of nitroalkanes to oximes in good yields. The selective synthesis of various linear, cyclic, and substituted oximes is described. The effectiveness of copper and silver salts is in the order, Cu(I) ≈ Cu(II) > Ag(I), for constant anion, with specific activity being particularly sensitive to the structure and basicity of the amine solvent and to the addition of π-acceptor ligands. For the synthesis of cyclohexanone oxime from nitrocyclohexane, catalyzed by solutions of copper(I) chloride in ethylenediamine, the proposed mechanism involving initial formation of cuprous hydride by hetcrolytic splitting of molecular hydrogen, followed by deoxygenation of the coordinated nitroalkane anion as a rate-determining step, is consistent with observed kinetics, deuterium isotope effects, and the use of complex metal hydrides as the hydride source." @default.
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- W2017111908 title "Homogeneous catalyzed reduction of nitrocompounds II. Hydrogenation to oximes" @default.
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- W2017111908 doi "https://doi.org/10.1016/0021-9517(74)90273-5" @default.
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