Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017130916> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2017130916 endingPage "820" @default.
- W2017130916 startingPage "811" @default.
- W2017130916 abstract "Cationic rhodium complexes of (R,R)-1,4-bis(diphenylphosphanyl)butane-2,3-diol and cyclic diolefins exhibit temperature-dependent 31P- and 103Rh-NMR spectra which are best explained by a hemilabile coordination of one of the hydroxy groups to the rhodium center. A complex with this ligand bound in tridentate fashion is in equilibrium with a species with the common square-planar ligand arrangement. The 103Rh-NMR shift of the fivefold coordinated complex is found almost 500 ppm downfield from that of a fourfold coordinated species. This effect is characteristic for an increase in coordination number. At gradient-corrected levels of density-functional theory, a corresponding species with an oxygen-rhodium contact has been located, together with other isomers. The computed trends in energies and 103Rh chemical shifts are consistent with the experimental findings." @default.
- W2017130916 created "2016-06-24" @default.
- W2017130916 creator A5015305457 @default.
- W2017130916 creator A5026992857 @default.
- W2017130916 creator A5048209419 @default.
- W2017130916 creator A5071858479 @default.
- W2017130916 date "1999-06-09" @default.
- W2017130916 modified "2023-09-23" @default.
- W2017130916 title "Variable Coordination Modes Realized with a Dihydroxyalkyldiphosphane as a Hemilabile Ligand: A Combined103Rh-NMR and Density-Functional Study" @default.
- W2017130916 doi "https://doi.org/10.1002/(sici)1522-2675(19990609)82:6<811::aid-hlca811>3.0.co;2-o" @default.
- W2017130916 hasPublicationYear "1999" @default.
- W2017130916 type Work @default.
- W2017130916 sameAs 2017130916 @default.
- W2017130916 citedByCount "17" @default.
- W2017130916 countsByYear W20171309162013 @default.
- W2017130916 countsByYear W20171309162018 @default.
- W2017130916 countsByYear W20171309162022 @default.
- W2017130916 crossrefType "journal-article" @default.
- W2017130916 hasAuthorship W2017130916A5015305457 @default.
- W2017130916 hasAuthorship W2017130916A5026992857 @default.
- W2017130916 hasAuthorship W2017130916A5048209419 @default.
- W2017130916 hasAuthorship W2017130916A5071858479 @default.
- W2017130916 hasConcept C103319777 @default.
- W2017130916 hasConcept C111429119 @default.
- W2017130916 hasConcept C116569031 @default.
- W2017130916 hasConcept C147597530 @default.
- W2017130916 hasConcept C147789679 @default.
- W2017130916 hasConcept C152365726 @default.
- W2017130916 hasConcept C161790260 @default.
- W2017130916 hasConcept C163111631 @default.
- W2017130916 hasConcept C170493617 @default.
- W2017130916 hasConcept C178790620 @default.
- W2017130916 hasConcept C183882617 @default.
- W2017130916 hasConcept C185592680 @default.
- W2017130916 hasConcept C2778717364 @default.
- W2017130916 hasConcept C2779463800 @default.
- W2017130916 hasConcept C521398313 @default.
- W2017130916 hasConcept C55493867 @default.
- W2017130916 hasConcept C71240020 @default.
- W2017130916 hasConcept C8010536 @default.
- W2017130916 hasConceptScore W2017130916C103319777 @default.
- W2017130916 hasConceptScore W2017130916C111429119 @default.
- W2017130916 hasConceptScore W2017130916C116569031 @default.
- W2017130916 hasConceptScore W2017130916C147597530 @default.
- W2017130916 hasConceptScore W2017130916C147789679 @default.
- W2017130916 hasConceptScore W2017130916C152365726 @default.
- W2017130916 hasConceptScore W2017130916C161790260 @default.
- W2017130916 hasConceptScore W2017130916C163111631 @default.
- W2017130916 hasConceptScore W2017130916C170493617 @default.
- W2017130916 hasConceptScore W2017130916C178790620 @default.
- W2017130916 hasConceptScore W2017130916C183882617 @default.
- W2017130916 hasConceptScore W2017130916C185592680 @default.
- W2017130916 hasConceptScore W2017130916C2778717364 @default.
- W2017130916 hasConceptScore W2017130916C2779463800 @default.
- W2017130916 hasConceptScore W2017130916C521398313 @default.
- W2017130916 hasConceptScore W2017130916C55493867 @default.
- W2017130916 hasConceptScore W2017130916C71240020 @default.
- W2017130916 hasConceptScore W2017130916C8010536 @default.
- W2017130916 hasIssue "6" @default.
- W2017130916 hasLocation W20171309161 @default.
- W2017130916 hasOpenAccess W2017130916 @default.
- W2017130916 hasPrimaryLocation W20171309161 @default.
- W2017130916 hasRelatedWork W1570576037 @default.
- W2017130916 hasRelatedWork W1868917088 @default.
- W2017130916 hasRelatedWork W2017130916 @default.
- W2017130916 hasRelatedWork W2047875079 @default.
- W2017130916 hasRelatedWork W2065523750 @default.
- W2017130916 hasRelatedWork W2080304034 @default.
- W2017130916 hasRelatedWork W2093603811 @default.
- W2017130916 hasRelatedWork W2951542948 @default.
- W2017130916 hasRelatedWork W3120391300 @default.
- W2017130916 hasRelatedWork W590328464 @default.
- W2017130916 hasVolume "82" @default.
- W2017130916 isParatext "false" @default.
- W2017130916 isRetracted "false" @default.
- W2017130916 magId "2017130916" @default.
- W2017130916 workType "article" @default.