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• W2017136237 abstract "The structure of 50PbO·50GaO1.5 and 80BiO1.5·20GaO1.5 glasses was investigated by neutron and X-ray diffraction. Most Ga3+ ions are four-coordinated in both glasses. PbO3 trigonal pyramids and PbO4 square pyramids are present in 50PbO·50GaO1.5 glass. The stronger glass-forming ability in PbOGaO1.5 is attributed to (PbO3, PbO4)n infinite spiral chains as in crystalline PbSiO3. Bi3+ ions form BiO5 and BiO6 units in 80BiO1.5·20GaO1.5 glass as in α-Bi2O3. This glass may be constructed by (BiO5, BiO6)n layers and GaO33− chains. It is assumed that in these glasses nearly all oxygen atoms bonded to Pb2+ or Bi3+ ions are three- or four-coordinated and most oxygen atoms bonded to Ga3+ ions are three-coordinated. It is found that the structure of the present ‘non-conventional’ glasses are contrary to Zachariasen's rules for glass formation." @default.
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• W2017136237 date "1994-10-01" @default.
• W2017136237 modified "2023-10-18" @default.
• W2017136237 title "Neutron and X-ray diffraction studies of PbOGa2O3 and Bi2O3Ga2O3 glasses" @default.
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• W2017136237 doi "https://doi.org/10.1016/0022-3093(94)90013-2" @default.
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