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- W2017149511 abstract "A novel approach is described for generating reactive oxidizing centers in heme proteins, with zinc hemoglobin (Zn Hb) and zinc cytochrome c (Zn cyt c) used as examples. The reaction of 3Zn* Hb with [CoIII(NH3)5 Cl]2+, and of 3Zn* cyt c with methyl viologen are described. In the case of Zn Hb the cation radical produced decays with a rate constant of k3 = 2400s-1. Using this value the rate of the reaction (formula; see text) can be calculated to be 4500s-1." @default.
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- W2017149511 date "1989-03-01" @default.
- W2017149511 modified "2023-09-26" @default.
- W2017149511 title "Photochemical generation and reactions of heme cation radicals in heme proteins" @default.
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- W2017149511 doi "https://doi.org/10.1016/0006-291x(89)90016-8" @default.
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