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- W2017149819 abstract "Abstract A new ultrachelating ligand, H4PYTA (3,6,14,17,23,24-hexaazatricyclo[17.3.1.1(8.12)]tetracosa-1(23),8,10,12(24),19,21-hexaene-3,6,14,17-tetraacetic acid), has been synthesized by tetracar-boxymethylation of the parent ligand PYAN (3,6,14,17,23,24-hexaazatricyclo[17.3.1.1(8.12)]tetracosa-1(23),8,10,12(24),19,21-hexaene). Both of these ligands are based upon the [18]aneN6 macrocyclic framework in which two trans dimethylamino groups are replaced by 2,6-substituted pyridine. The metal binding constants for PYTA4- (log KML) were measured for sixteen metals and were found to be comparable to those for DTPA5- and DOTA4-. PYTA4- binds well to an extraordinarily large range of metal ions from small Ga3+ to large Pb2+. This behavior is attributable to the flexible wrapping of the PYAN framework and the ability of PYTA4- to be six-coordinate with small metals and ten-coordinate with large metals." @default.
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- W2017149819 date "1996-03-01" @default.
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- W2017149819 title "Design and synthesis of an “ultrachelating” ligand based on an 18-membered ring hexaaza macrocycle" @default.
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- W2017149819 doi "https://doi.org/10.1080/10610279608032556" @default.
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