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- W2017156729 abstract "Abstract The vast amount of research on the B 12 coenzyme catalysed 1,2-bond shift reactions now provides strong evidence for the conclusion that spin-spin coupled biradical intermediates (R · … · [Co]) are responsible for the facile rearrangements involved via π-complexed (charge–transfer complexed) half-reaction states. The biradical intermediates are also likely to be involved in stereospecific [2+2] activation of the substrates." @default.
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- W2017156729 date "2000-12-01" @default.
- W2017156729 modified "2023-09-27" @default.
- W2017156729 title "Biradical mechanism of the 1,2-bond shift reaction catalysed by vitamin B12 coenzyme" @default.
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- W2017156729 doi "https://doi.org/10.1016/s1381-1169(00)00265-x" @default.
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