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- W2017161504 abstract "Precipitation with bromides, thiocyanates and iron cyanides was investigated to recover Pd and Ag from process solutions obtained by hydrochemical reprocessing of secondary raw materials with precious metals contents. By combined precipitation with thiocyanate/iron cyanides a reproducible Pd and Ag recovery was achieved from nitric acid solutions containing, besides the precious metals, large amounts of Cu, Zn, Fe, Sn and Pb (final contents < 5 mg 1−1). From solutions containing complexing ions such as Cl− and NO2− and, consequently, Pd in the form of anionic complexes, palladium could not be separated by the use of those precipitants. In this case palladium could largely be precipitated by the addition of excessive thiocyanate in the presence of non-ferrous cations. The concentrates obtained can subsequently be treated by the traditional process of precious metal separation to obtain the refined metals." @default.
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- W2017161504 date "1989-05-01" @default.
- W2017161504 modified "2023-10-16" @default.
- W2017161504 title "Recovery of palladium and silver from process solutions by precipitation with thiocyanates and iron cyanides" @default.
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- W2017161504 doi "https://doi.org/10.1016/0304-386x(89)90003-0" @default.
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