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• W2017177517 abstract "The absolute rate constants for the reactions of chlorine atoms with (CH3)3SiOSi(CH3)3, (CH3)2HSiOSiH(CH3)2, and (CH3)H2SiOSiH2(CH3) were measured in the gas phase over the temperature range 273–363 K, using the very low pressure reactor (VLPR) in a molecular flow system. The absolute rate constants were temperature independent and take the values (in cm3molecule−1s−1, 2σ uncertainties): k1=(1.00±0.19)×10−10,k2=(1.98±0.29)×10−10, and k3=(2.42±0.25)×10−10. All title reactions proceed via the abstraction of C–H and/or Si–H hydrogen leading to the formation of HCl. The results show that the reactivity of Si–H bond towards Cl atom attack is higher than the reactivity of the C–H bond." @default.
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• W2017177517 date "2001-08-01" @default.
• W2017177517 modified "2023-09-27" @default.
• W2017177517 title "Kinetic study for the reactions of chlorine atoms with hexamethyldisiloxane, 1,1,3,3-tetramethyldisiloxane, and 1,3-dimethyldisiloxane" @default.
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• W2017177517 doi "https://doi.org/10.1016/s0009-2614(01)00713-8" @default.
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