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- W2017180842 abstract "Measurements have been made of the magnetic susceptibility X in ternary titanium-vanadium hydrides Ti1−yVyHx in the range 0<y< 0.5 and with a hydrogen to metal ratio from 1.6 to 1.92; they cover the temperature interval from 80 to 440 K. The x−T curves of some of the ternary hydrides possess a maximum similar to that seen in binary hydrides. Its occurrence depends upon both hydrogen and vanadium concentration. Comparison with the lattice constants shows that this dependence is related to the transition from the cubic γ-phase to the tetragonal δ-phase. The x−T curves of those samples showing the phase transition were extrapolated from the cubic phase down to lower temperatures. Conclusions were drawn from the measured and extrapolated susceptibility values, as to the influence of both hydrogen and vanadium concentrations on the electronic structure of these hydrides. The dependence of the magnetic susceptibility on the vanadium concentration shows that, in the cubic phase, the fermi energy lies on the increasing side of a maximum in the density of states curve. The degree of occupation of the conduction band does not depend on the hydrogen concentration. The rigid band model cannot be used in the hydrides studied here to account for the effects of varying their hydrogen concentration." @default.
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- W2017180842 title "Antiferromagnetism in titanium hydride" @default.
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- W2017180842 doi "https://doi.org/10.1016/0001-6160(58)90131-7" @default.
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