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- W2017183467 abstract "The solid/liquid interface can often be modeled by the familiar equivalent circuit consisting of a solution resistance in series with a parallel combination of the double-layer capacitance C and the resistance to charge transfer Rp. For this model, when plots of the imaginary part vs the real part of the complex impedance produce depressed semicircles (Cole-Cole plots), the centers of which lie below the real axis, then the relaxation time of the equivalent RC circuit is distributed around a most probable value τ0 = CRP, with the degree of departure from ideality given by an appropriate parameter α. Four methods are developed to calculate C and α from Cole-Cole plots, and these methods are illustrated both for model systems and experimental data." @default.
- W2017183467 created "2016-06-24" @default.
- W2017183467 creator A5015295223 @default.
- W2017183467 date "1997-02-01" @default.
- W2017183467 modified "2023-10-16" @default.
- W2017183467 title "On the determination of distributed double-layer capacitances from cole-cole plots" @default.
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- W2017183467 doi "https://doi.org/10.1016/s0010-938x(97)83345-8" @default.
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