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- W2017188380 abstract "Abstract The stable hydrochalcogenide [(pp3)Rh(XH)] complexes (pp3 = tris(2-diphenylphosphinoethyl)phosphine; X S (1), Se (2)) have been prepared by treatment of [RhCl(cod)]2 with hydrochalcogenide solutions in the presence of pp3. The two compounds react with CF3SO3H to yield the rare cis-hydride-hydrochalcogenide [(pp3)Rh(H)(XH)]CF3SO3 compounds (X S (3), Se (4)), which appear to be formed through an internal oxidative addition." @default.
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- W2017188380 date "1987-10-01" @default.
- W2017188380 modified "2023-09-27" @default.
- W2017188380 title "Hydrochalcogenide and hydride-hydrochalcogenide complexes of rhodium with the tripodal tetraphosphine pp3" @default.
- W2017188380 doi "https://doi.org/10.1016/s0022-328x(00)99821-8" @default.
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