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- W2017197745 abstract "Abstract The polarographic and voltammetric behaviour of cis-[Co(en)2(enH)Cl]Cl3 · H2O and [Co(en)3]Cl3 in water and dimethylsulphoxide has been investigated at a dropping mercury electrode, a hanging mercury drop electrode and a Pt planar electrode. The mechanism for electrochemical conversion of the protonated, partly-chelated cis-[Co(en)2(enH)Cl]3 + complex into [Co(en)3]3+ was established on the basis of dynamic electrochemistry investigations. For the second step of the reduction, [Co(en)ienH]3+ to Co(Hg), the electrode reaction mechanism varies with changes in the degree of complcxation. Reduction of Co(II) in ethanediamine/2-aminoethylammonium buffer solution in the presence of a small amount of human blood serum at nearly neutral pH is catalytic in nature." @default.
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- W2017197745 date "1995-02-01" @default.
- W2017197745 modified "2023-10-16" @default.
- W2017197745 title "DYNAMIC ELECTROCHEMISTRY OF CIS-[Co(EN)2(ENH)Cl]Cl3· H2O AND [Co(EN)3]Cl3COMPLEXES" @default.
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- W2017197745 doi "https://doi.org/10.1080/00958979508055390" @default.
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