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- W2017198028 abstract "Hyperfine magnetic interactions have been observed for the first time for Sn2+ ions introduced as doping agents in a magnetically ordered oxide (119Sn: Cr2O3). Mössbauer resonance at low temperature shows for 119Sn2+ the simultaneous presence of hyperfine magnetic and quadrupole interactions, which have the same order of magnitude at 77 K. From the spectra, the following parameters have been determined: tranfered hyperfine magnetic field: HSn2+ (77 K = 38 ± 1kOe, sign and value of the quadrupole interaction constant: eVzzQ = + 3,6 ± 0,3 mm/s, asymmetry parameter: η = 0,15 ± 0,05, polar (θ) and azimutal (ϕ) angles: θ ⋍ ϕ ⋍ 90°, and chemical shift: δBaSnO3 = + 2,89 ± 0,02 mm/s. The investigation shows that Sn2+ is localized at the surface of the Cr2O3 grains." @default.
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- W2017198028 date "1981-04-01" @default.
- W2017198028 modified "2023-09-24" @default.
- W2017198028 title "Interactions magnetiques hyperfines et quadrupolaires combinees pour les ions d'impuretes 119Sn2+ dans Cr2O3" @default.
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- W2017198028 doi "https://doi.org/10.1016/0025-5408(81)90011-8" @default.
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