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- W2017200449 abstract "Abstract The extraordinary mechanical and swelling/deswelling properties of nanocomposite (NC) gels are attributed to their unique organic (polymer)/inorganic (clay) network structure. In this study, poly( N ‐isopropylacrylamide) (PNIPA) was successfully separated from an NC gel network by decomposing the clay (hectorite) using hydrofluoric acid (HF). A very low HF concentration (0.2 wt.‐%) was adequate for the decomposition of the clay without causing any damage to PNIPA. The separated PNIPA had a high $overline M _{rm w}$ (=5.5 × 10 6 g · mol −1 ). Also, $overline M _{rm w}$ was almost constant regardless of the clay concentration ( C clay = 1–25 × 10 −2 mol · l −1 ), even though the properties of the NC gel varied widely over this C clay range. Comparisons of NC gels, PNIPA, and SiO 2 ‐NC gels indicated that the clay platelets specifically play an important role in NC gels. magnified image" @default.
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- W2017200449 date "2010-04-15" @default.
- W2017200449 modified "2023-10-16" @default.
- W2017200449 title "Molecular Characteristics of Poly(<i>N</i> -isopropylacrylamide) Separated from Nanocomposite Gels by Removal of Clay from the Polymer/Clay Network" @default.
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- W2017200449 doi "https://doi.org/10.1002/marc.200900819" @default.
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