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- W2017200523 abstract "The extraction of copper(II) was carried out with lipoic acid in benzene at 25 °C and at a constant ionic strength in the aqueous phase: 0.1 mol dm−3 (NaNO3). The partition constant, KD,HA of lipoic acid between benzene and water, and the dimerization constant, K2,HA of lipoic acid in benzene were determined: logKD,HA=1.17 and logK2,HA=2.51 The dimeric copper(II) lipoate is responsible for the extraction: 2Cu2++3(HA)2,ooversetKex(22)ightleftharpoons(Cu2A4(HA)2)o+4H+ with the extraction constant, logKex(22)=−11.00. It was proved that lipoate ion coordinates to copper(II) with the carboxylate group without a remarkable participation of the disulfide moiety in the coordination." @default.
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- W2017200523 date "1986-12-01" @default.
- W2017200523 modified "2023-09-26" @default.
- W2017200523 title "Solvent Extraction of Copper(II) with Lipoic Acid in Benzene. Evidence for the Preferential Coordination of Carboxylate" @default.
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- W2017200523 doi "https://doi.org/10.1246/bcsj.59.3855" @default.
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