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- W2017200707 abstract "Ether lipids are macromolecules with ether bonds that combine hydrocarbon side chains to the glycerol molecule. Isoprenoid glycerol ether lipids are unique to archaebacteria. These micro-organisms inhabit anoxic, hypersaline and hydrothermal environments that are fatal to all other living organisms. Chemically, archaebacterial glycerol ether lipids do not biodegrade easily and can exist as “chemical fossils”. In order to understand geochemical transformation of glycerol ether lipids in sediments and sedimentary rocks, thermal stress was induced on glycerol ether lipid molecules by flash and hydrous pyrolysis processes. Pyrolysis processes induce chemical changes in glycerol ether lipid molecules. Isoprenoid alcohols and isoprenoid hydrocarbons were primary pyrolysis products formed as a result of thermal degradation of archaebacterial glycerol ether lipids. Milder pyrolysis conditions lead to the formation of isoprenoid alcohols only. Flash pyrolysis experiments showed that by increasing thermal stress on ether lipids, greater yields of lower molecular weight hydrocarbons were produced. Based on pyrolysis—gas chromatography/mass spectrometry results, a mechanism for transformation of glycerol ether lipid molecules to hydrocarbons is proposed." @default.
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- W2017200707 date "1992-08-01" @default.
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- W2017200707 title "A study of chemical transformation of glycerol ether lipids to hydrocarbons by flash and hydrous pyrolysis" @default.
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- W2017200707 doi "https://doi.org/10.1016/0165-2370(92)85001-2" @default.
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