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- W2017202483 abstract "Pyridine N-oxide complexes having the composition ZrO(Py • O) 6 (ClO 4 ) 2 , Th(Py • O) 8 (ClO 4 ) 4 , and UO 2 (Py • O) 5 (ClO 4 ) 2 have been prepared. The infrared and electronic absorption spectra show that the bonding between the metal and pyridine N-oxide in the complexes has occurred by donation of the lone pair of p-electrons on oxygen to the metal, and that the π-bond character of NO group increases in the complexes as uranyl < thorium < zirconyl. The decrease in the vibrational structure of the UO 2 2+ spectrum in the visible region indicates strong coordination of pyridine N-oxide to the uranyl group. The decomposition temperatures of zirconyl, thorium, and uranyl complexes are 307, 350, and 319 °C respectively." @default.
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- W2017202483 modified "2023-10-12" @default.
- W2017202483 title "PYRIDINE N-OXIDE COMPLEXES OF ZIRCONYL, THORIUM, AND URANYL PERCHLORATES" @default.
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- W2017202483 doi "https://doi.org/10.1139/v64-127" @default.
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