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• W2017203431 abstract "Exchange reactions between 0.0in AlCl3 solutions of different pH and Ca-saturated montmorillonite, vermiculite, illite, and soils from the Park Grass Experiment at Rothamsted and the Deerpark Experiment, Wexford, Ireland, showed that Al3+ and Al(OH)2+ were adsorbed from solutions of pH > 4.0 and Al3+ and H+ from solutions of pH < 3.0. When Al was adsorbed, the cation exchange capacity of Ca-saturated soils and clays increased. Conventional Ca: Al exchange isotherms showed that Al3+ was strongly preferred to Ca2+ on all soils and clays. The equilibrium constant for Ca: Al exchange, K, was identical for soils before and after oxidizing their organic matter and did not vary, for any exchanger, with Al-saturation or the initial pH of the AlCl3 solution. This proved the validity of the procedure used for calculating exchangeable Al3+. K values for Ca:Al exchange favoured Al3+ in the order: vermiculite > Park Grass soil > Deerpark soil > illite > montmorillonite. The influence of surface-charge densities of the clay minerals on this order is discussed and a method proposed and tested for calculating the K value of a soil from its mineralogical composition." @default.
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• W2017203431 date "1968-09-01" @default.
• W2017203431 modified "2023-09-24" @default.
• W2017203431 title "CALCIUM: ALUMINIUM EXCHANGE EQUILIBRIA IN CLAY MINERALS AND ACID SOILS1" @default.
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• W2017203431 doi "https://doi.org/10.1111/j.1365-2389.1968.tb01537.x" @default.
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